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【一问】关于Fe 2+与亚铁氰化钾反应产物的疑问

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反应产生天蓝色沉淀,用氧化剂氧化后变成深蓝色,试问,天蓝色产物是什么?


1楼2013-10-26 22:38回复
    WIki到这一段话
    “Prussian blue is produced by oxidation offerrous ferrocyanide salts. These white solids have the formula M2Fe[Fe(CN)6]where M+ = Na+ or K+. The iron in thismaterial is all ferrous, hence the absence of deep color associated with themixed valency. Oxidation of this white solid with hydrogen peroxide or sodiumchlorate produces ferricyanide and affords Prussian Blue.”


    2楼2013-10-26 22:39
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      二价铁应该是和铁氰化钾反应吧


      IP属地:北京3楼2013-10-26 22:40
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        K+ + Fe3+ + [FeII(CN)6]4- → KFeIII[FeII(CN)6]
        发那个表情让人觉得很欠揍.


        IP属地:广东4楼2013-10-26 22:41
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          你的题目搞错了,反应物不可能都是2价的铁,不然化合价没变化,怎么是叫化学反应?


          来自手机贴吧8楼2013-10-26 22:51
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